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The higher the temperature, the higher the typical level
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Collisions can knock electrons to higher levels,
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if moving atoms have enough kinetic energy
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At T ~ 300 K (room
T) almost all H in ground state
(n=1)
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At T ~ 10,000 K many H are in first excited state (n=2)
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At T ~ 15,000 K many H are ionized
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Because you have highest n=2 population at ~10,000K
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you also have highest Balmer line strength there.
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This gives us another way to estimate temperatures of stars
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